SYSCO CHEMICAL -- RELIANCE BLEACH JR-570 -- 6850-00F031108
===================== Product Identification ===================== Product ID:RELIANCE BLEACH JR-570 MSDS Date:11/01/1991 FSC:6850 NIIN:00F031108 === Responsible Party === Company Name:SYSCO CHEMICAL Address:1390 ENCLAVE PKWY City:HOUSTON State:TX ZIP:77077 Country:US Info Phone Num:713-584-1790 Emergency Phone Num:713-584-1790 CAGE:SYSCO === Contractor Identification === Company Name:SYSCO CHEMICAL Address:1390 ENCLAVE PARKWAY Box:City:HOUSTON State:TX ZIP:77077 Country:US Phone:713-584-1790 CAGE:SYSCO ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYPOCHLORITE, HYPOCHLOROUS ACID SODIUM SALT CAS:7681-52-9 RTECS #:NH3486300 Fraction by Wt: 5-7% EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 12 G/KG (SEE SUPP DATA) Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: LIQUID/MIST CONTACT CAN PRODUCE SEVERE IRRITATION. SKIN: LIQUID CONTACT CAN PRODUCE BLISTERING & ECZEMA. INGESTION: CAN CAUSE CORROSION OF MUCOUS MEMBRANES & PERFORATION OF ESOPHAGUS & STOMACH. INHALATION: MIST/FUMES CAN CAUSE BRONCHIAL IRRITATION, COUGHING, DIFFICULT BREATHING, NAUSEA & PULMONARY EDEMA. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: LIQUID/MIST CONTACT CAN PRODUCE SEVERE IRRITATION. SKIN: LIQUID CONTACT CNA PRODUCE BLISTERING & ECZEMA. INGESTION: CAN CAUSE CORROSION OF MUCOUS MEMBRANES, PERFORATION OF ESOPHAGUS & STOMACH. I NHALATION: MIST/FUMES CAN CAUSE BRONCHIAL IRRITATION, COUGHING, DIFFICULT BREATHING, NAUSEA & PULMONARY EDEMA. ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE W/WATER FOR AT LEAST 15 MINS. SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: RINSE MOUTH W/WATER. DRINK LARGE QUANTITIES OF WATER/MILK. DON'T INDUCE VOMITING. DON'T USE ACIDIC ANTIDOTES/SODIUM BICARBONATE. OBTAIN MEDICAL ATENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:APPROPRIATE FOR SURROUNDING FIRE Fire Fighting Procedures:USE WATER SPRAY FROM SAFE DISTANCE TO COOL EXPOSED CONTAINERS, DILUTE LIQUID, CONTROL VAPORS. WEAR FULL PROTECTIVE CLOTHING & SCBA. REMOVE CONTAINERS FROM AREA. Unusual Fire/Explosion Hazard:SODIUM HYPOCHLORITE IS AN OXIDIZING AGENT & VIGOROUS REACTIONS CAN OCCUR W/OXIDIZABLE MATERIALS IN A FIRE SITUATION. CAN BE DECOMPOSED BY HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN & RECOVER. PREVENT LIQUID FROM ENTERING SEWERS/WATERWAYS. CLEAN-UP PERSONNEL SHOULD USE PROTECTIVE EQUIPMENT TO PREVENT CONTACT. DON'T USE COMBUSTIBLE ABSORBENTS. Neutralizing Agent:HYPOCHLORITE CAN BE NEUTRALIZED W/WEAK REDUCING AGENTS. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN CONTAINERS IN A COOL, DRY, WELL VENTILATED AREA AWAY FROM DIRECT SUNLIGHT, HEAT & INCOMPATIBLE MATERIALS. STORE <85F. Other Precautions:PROTECT CONTAINERS FROM PHYSICAL DAMAGE. THIS PRODUCT DEGRADES W/AGE. USE A CHLORINE TEST KIT & INCREASE DOSAGE AS NECESSARY TO OBTAIN THE REQUIRED LEVEL OF AVAILABLE CHLORINE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATORY PROTECTION. FOR CANNISTER-TYPE RESPIRATORS, USE CHLORINE FILTERS. Ventilation:LOCAL TO REMOVE VAPORS AT SOURCE. DON'T RELY ON GENERAL EXHAUST. Protective Gloves:IMPERVIOUS, POLYVINYL CHLORIDE (SUPP) Eye Protection:CHEMICAL GOGGLES Other Protective Equipment:CHEMICAL RESISTANT CLOTHING Supplemental Safety and Health ORAL LD50 DATA IS FOR A 12% AQUEOUS SOLUTION OF SODIUM HYPOCHLORITE. PH: 11.5-13. GLOVES CONT'D: TAPED TO CLOTHING. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE SUPP Vapor Pres:17.5 Spec Gravity:1.08 pH:SUPP Solubility in Water:COMPLETE Appearance and Odor:CLEAR, PALE YELLOW/GREENISH LIQUID W/A CHLORINE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ANY ACID MATERIAL, AMMONIA, UREA, OXIDIZABLE MATERIALS & METALS SUCH AS NICKEL, COPPER, TIN, ALUMINUM & IRON Stability Condition to Avoid:HEAT, TEMPS >85F, DIRECT SUNLIGHT Hazardous Decomposition Products:CHLORINE GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN A PERMITTED DISPOSAL FACILITY IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.