MALLINKRODT BAKER INC -- ZINC SULFATE, 7-HYDRATE, 8872 -- 6810-00N088718
===================== Product Identification ===================== Product ID:ZINC SULFATE, 7-HYDRATE, 8872 MSDS Date:02/15/1998 FSC:6810 NIIN:00N088718 Status Code:A === Responsible Party === Company Name:MALLINKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC) CAGE:IO255 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 Company Name:MALLINKRODT BAKER INC Address:222 RED SCHOOL LANE Box:M City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:IO255 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC SULFATE (SARA 313) (CERCLA) CAS:7733-02-0 RTECS #:ZH5260000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUP DAT: OF THE EXTREMITIES. REPEATED SKIN OR EYE CONTACT CAN CAUSE SKIN AND EYE EFFECTS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: GET MED ATTN. WASH CLOTHING BEFORE REUSE. THORO CLEAN SHOES BEFORE REUSE. EYES: IMMED FLUSH (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: WITH PLENTY OF WATER FOR AT LEAST 15 MIN, LIFTING LOWER & UPPER EYELIDS OCCASIONALLY. GET MED ATTN IMMED. RTECS #:9999999ZZ Ingred Name:SPILL PROC: SOLN. US REGS (CERCLA) REQUIRE REPORTING SPILLS & RELEASES TO SOIL, WATER & AIR IN EXCESS OF (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: REPORTABLE QUANTITIES. THE TOLL FREE NUMBER FOR THE US COAST GUARD NATIONAL RESPONSE CENTER IS (800) 424-8802. RTECS #:9999999ZZ Ingred Name:RESP PROT: WARNING: AIR-PURIFYING RESPIRATORS TO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES. RTECS #:9999999ZZ Ingred Name:VENT: IT CAN CTL EMISSIONS OF CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA. (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: PLEASE REFER TO ACGIH DOCUMENT, INDUS VENT, A MANUAL OF RECOMMENDED PRACTICES, MOST RECENT EDITION, FOR DETAILS. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: DISPOSE OF CONTAINER AND UNUSED CONTENTS IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 1710 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: IRRIT TO RESP TRACT. SYMPS MAY INCL COUGHING, SHORTNESS OF BREATH. INGEST: AS W/OTHER SOL ZINC SALTS, ZINC SULFATE MAY HYDROLYZE INTO ACID IF SWALLOWED. SEV IRRIT & BURNS OF MOUTH, THROA T & DIGESTIVE SYS MAY OCCUR. SYMPS MAY INCL VOMIT, STOM PAIN, INCRD PULSE RATE W/BLOOD PRESS DECR, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: BLOOD PRESS DECR, ACUTE PULM EDEMA (FLUID IN LUNGS), DIARR, KIDNEY DMG, OTHER GI DISTURBS & HEMORR PANCREATITIS. FATALITY FOLLOWING INGEST OF 10 GRAMS HAS BEEN REPORTED. SKIN: CAUSES IRRIT. SYMPS INCL REDNESS, ITCH, & PAIN. EYES:IRRITANT. CAN CAUSE PAIN & REDNESS, POSS MECH HARM. MAY CAUSE SEV (SUP DAT) Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING SKIN DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. GET MED ATTN. INGEST: GIVE SEVERAL GLASSES OF WATER TO DRINK. VOMIT MAY OCCUR SPONT, BUT DO NOT INDUCE! NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. GET MED ATTN. SKIN: WIPE OFF EXCESS MATL FROM SKIN THEN IMMED FLUSH SKIN W/PLENTY OF WATER FOR AT LEAST 15 MIN. REMOVE CONTAM CLTHG & SHOES. (ING 3) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTING SURROUNDING FIRE. USE WATER CAREFULLY AS MATL WILL REACT W/WATER TO FORM (SUP DAT) Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:ZINC SULFATE CAN DECOMPOSE AT HIGH TEMPS TO FORM TOX OXIDES, SULFUR & ZINC OXIDE AS WELL AS WATER VAP. SEALED CONTRS MAY RUPTURE AT MOD TEMPS (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA OF LEAK/SPILL. KEEP UNNEC & UNPROT PEOPLE AWAY FROM AREA OF SPILL. WEAR APPROP PERS PROT EQUIP. PICK UP & PLACE IN SUITABLE CONTR FOR RECLAMATION/DISP, USING METH THAT DOES NOT GENERATE DUST . MATL DISSOLVES IN WATER TO FORM ACIDIC (ING 5) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CONTR, STORED IN COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DMG. MATL DISSOLVES IN WATER TO FORM ACIDIC SOLUTION. Other Precautions:CONTRS MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PROD RESIDUES (DUST, SOLIDS): OBSERVE ALL WARNINGS & PREC LISTED. AVOID BREATHING DUST. USE ONLY W/ADEQ VENT. AVOID CONT W/EYES, SKIN & CLOTHING. W ARNING! HARMFUL IF SWALLOWED/INHALED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CNDTNS OF USE WHERE EXPOS TO DUST/MIST IS APPARENT, A NIOSH APPRVD HALF-FACE DUST/MIST RESP MAY BE WORN. FOR EMER/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPRVD FULL-FACE POSS-PRESS, AIR-SUPPLIED RESP. (ING 7) Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS AS LOW AS POSS. LOC EXHST VENT IS GEN PREF BECAUSE (ING 8) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER . WEAR IMPERVIOUS PROT CLOTHING, BOOTS, LAB COAT, APRON/COVERALLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EXTING MEDIA: ACIDIC SODIUM. WATER SPRAY MAY BE USED TO KEEP FIRE-EXPOSED CONTRS COOL. EXPLO HAZ: (RELEASE OF WATER VAP). FORMS ACIDIC SOLNS IN WATER. EFTS OF OVEREXP: IRRIT. CHRONIC EXPOS MAY CAUSE F ATG, SLOW TENDON REFLEXES, INTESTINAL INFLAMM (W/BLEEDING), DIARR, BLOOD EFTS, CNS DEPRESS, TREMORS & PARALYSIS (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>932F,>500C Melt/Freeze Pt:M.P/F.P Text:212F,100C Spec Gravity:1.97 pH:4.5 Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS CRYSTALS OR GRANULES, ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES LEAD, CALCIUM, STRONTIUM SALTS, ALKALI CARBONATES AND HYDROXIDES, SILVER PROTEIN AND TANNINS. Stability Condition to Avoid:HEAT, MOISTURE, INCOMPATIBLES. Hazardous Decomposition Products:OXIDES OF SULFUR AND OXIDES OF ZINC. REACTS WITH WATER TO FORM SULFURIC ACID. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP & APPRVD WASTE DISP FACILITY. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOC DISP REGS MAY DIFFER FROM FED DISP REGS. (ING 10) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.