MARCHEM CORP -- MISTABOND H3164 -- 8040-00N091508
===================== Product Identification ===================== Product ID:MISTABOND H3164 MSDS Date:08/25/1993 FSC:8040 NIIN:00N091508 Status Code:A === Responsible Party === Company Name:MARCHEM CORP Address:2500 ADIE RD City:MARYLAND HEIGHTS State:MO ZIP:63043 Country:US Info Phone Num:314-872-8700 Emergency Phone Num:(800)424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:MARCH === Contractor Identification === Company Name:MARCHEM CORP Address:2500 ADIE RD Box:City:MARYLAND HEIGHTS State:MO ZIP:63043 Country:US Phone:314-872-8700 CAGE:MARCH ============= Composition/Information on Ingredients ============= Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (METHYLENE BISPHENYL ISOCYANATE) CAS:101-68-8 RTECS #:NQ9350000 Minumum % Wt:18. Maxumum % Wt:24. OSHA PEL:C0.2 MG/M3;C0.02 PPM ACGIH TLV:0.051 MG/M3;.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF MUCOUS MEMBRANES, RUNNING NOSE, SORE THROAT, COUGH, A REDUCTION IN LUNG FUNCTION, BRONCHITIS, BRONCHIAL SPASM AND PULMONARY EDEMA. SKIN: REDDENING, SWELLING, BLISTERING, DERM ATITIS. EYES: IRRITATING; CAN CAUSE LACRYMATION; CORNEAL DAMAGE CAN OCCUR. Effects of Overexposure:INHALATION: MAY CAUSE BREATHLESSNESS, IRRITATION AND REDUCED PULMONARY FUNCTION. REACTION MAY BE DELAYED 4-8 HOURS. SENSITIVITY MAY DEVELOP LEADING TO ASTHMA-LIKE SYMPTOMS. Medical Cond Aggravated by Exposure:ASTHMATIC-TYPE CONDITIONS. CHRONIC BRONCHITIS, CHRONIC RESPIRATORY DISEASES. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INHALATION: REMOVE TO FRESH AIR. IF BREATHING DIFFICULT ADMINISTER OXYGEN. IF STOPPED, APPLY ARTIFICIAL RESPIRATION. EYES: FLUSH WITH WATER F OR AT LEAST 15 MINUTES. CONSULT DOCTOR. INGESTION: DO NOT INDUCE VOMITING. GIVE 250 ML MILK OR WATER TO DRINK. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>148.9C, 300.F Extinguishing Media:WATER FOG, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:AVOID WATER CONTAMINATION IN CLOSED CONTAINERS ON CONFINED SPACES (CO*2 EVOLVED). ================== Accidental Release Measures ================== Spill Release Procedures:PROPERLY PROTECTED PERSONNEL SHOULD CONTAIN AND COVER SPILL WITH ABSORBENT MATERIAL. PLACE IN OPEN CONTAINER. REMOVE TO WELL VENTILATED AREA AND DILUTE WITH AMMONIA SOLUTION (WATER 90%, NH*4OH 8%, DET ERGENT 25%). LEAVE VENTILATED 24 HOURS. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID MOISTURE CONTAMINATION. STORE UNDER 40F DEW POINT. Other Precautions:AVOID RAPID OR EXCESSIVE HEAT. DO NOT EXCEED 225 PSIG IF PACKAGED IN PRESSURIZED CYLINDERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED PRESSURE DEMAND SUPPLIED AIR BREATHING APPARATUS IF PEL OR TLV EXCEEDED. Ventilation:LOCAL EXHAUST: PREFFERED. MECHANICAL (GENERAL): TO MAINTAIN BELOW TLV. SPECIAL: N/A. OTHER: N/A. Protective Gloves:RUBBER OR PLASTIC GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:IF CONTAINER IS EXPOSED TO HIGH HEAT, IT CAN BE PRESSURIZED & POSSIBLY RUPTURE. MDI REACTS SLOWLY W/WATER TO FORM CARBON DIOXIDE GAS. THIS GAS CAN CAUSE SEALED CONTAINER TO EXPAND & POSSIBLY RUPTURE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Density:>1(AIR=1) Spec Gravity:1.1 (H*2O=1) Solubility in Water:REACTS Appearance and Odor:BROWN LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, STRONG BASES, ALCOHOLS, METAL COMPOUNDS. Stability Condition to Avoid:AVOID TEMPERATURES GREATER THAN 120F OR BELOW 50F. Hazardous Decomposition Products:CO, OXIDES OF NITROGEN, TRACES OF HCN, MDI. Conditions to Avoid Polymerization:CONTAMINATION BY MOISTURE OR OTHER MATERIAL THAT REACT WITH ISOCYANATES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT/UN SHIPPING NAME: ADHESIVE. DOT HAZARD CLASS: NON-HAZARDOUS. DOT/UN HAZARD NUMBER: NONE REQUIRED. DOT PLACARD: NONE REQUIRED. ===================== Regulatory Information ===================== SARA Title III Information:THIS MATERIAL FITS THE EPA HAZARD CATEGORY DEFINITION OF IMMEDIATE (ACUTE) AND DELAYED (CHRONIC) HEALTH HAZARDS UNDER SARA (SECTIONS 311 AND 312). SARA SECTION 313 TOXIC CHEMICALS FOR REPORTING: ETHYL ENE GLYCOL CAS 107-21-1, 2%, METHANOL CAS 67-56-1, 1-2%. Federal Regulatory Information:CHEMICAL SUBSTANCES HAVE BEEN REPORTED TO THE EPA OFFICE OF TOXIC SUBSTANCES IN ACCORDANCE WITH THE REQUIREMENTS OF THE TOXIC CHEMICAL SUBSTANCES CONTROL ACT (TITLE 40 CFR 710). State Regulatory Information:CALIFORNIA PROPOSITION 65 LISTED CHEMICALS: NONE KNOWN. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.