MALLINCKRODT BAKER INC -- N-BUTYRIC ACID, 0098 -- 6810-00N092121
===================== Product Identification ===================== Product ID:N-BUTYRIC ACID, 0098 MSDS Date:12/08/1996 FSC:6810 NIIN:00N092121 Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC) Resp. Party Other MSDS Num.:B7612 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:BUTYRIC ACID CAS:107-92-6 RTECS #:ES5425000 = Wt:100. EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 2000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:DEPENDING ON CONTACT AREAS AND EXPOSURE, N-BUTYRIC ACID CAN ACT AN IRRITANT OR AS A CORROSIVE. INHALATION: VAPORS IRRITATE THE RESPIRATORY TRACT. SYMPTOMS INCLUDE SORE THROAT, COUGHING AND SHORTNESS O F BREATH. INGESTION: CORROSIVE MAY CAUSE TISSUE DAMAGE. SKIN CONTACT: CORROSIVE. CAUSES SKIN BURNS. MAY BE ABSORBED THROUGH THE SKIN. EYE CONTACT: CORROSIVE. VAPORS IRRITATE THE EYES. SPLASHES MAY CAU SE EYE DAMAGE. CHRONIC: NO INFORMATION FOUND. Effects of Overexposure:SEE HEALTH HAZARD. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. SKIN CONTACT: REMOVE ANY CONTAMINATED CLOTHING AND SHOES. WASH SKIN WITH SOAP OR MILD DETERGENT AND WATER FOR A T LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER AND UPPER EYELIDS OCCASIONALLY. GET MED ICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=72.C, 161.6F Autoignition Temp:=440.C, 824.F Lower Limits:2% Upper Limits:10% Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. EXPLOSION: ABOVE FLASH POINT, VAPOR-AIR MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS NOTED ABOVE. NFPA RATINGS: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 0. HEALTH RATING: 1 - SLIGHT . FLAMMABILITY RATING: 2 - MODERATE. REACTIVITY RATING: 1 - SLIGHT. CONTACT RATING: 3 - SEVERE (CORROSIVE). ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA OF LEAK/SPILL. REMOVE ALL SOURCES OF IGNIT. WEAR APPROP PERS PROT EQUIP AS SPECIFIED IN SECTION 8. ISOLATE HAZ AREA. KEEP UNNEC & UNPROTECTED PERS FROM ENTERING. CNTN & RECOVER LIQ WHEN POSS . USE NON-SPARKING TOOLS & EQUIP. COLLECT LIQ IN APPROP CNTNR/ABSORB W/INERT MATL (E G, VERMICULITE, DRY SAND, EARTH), & PLACE IN CHEM WASTE CNTNR. DO NOT USE COMBUST MATLS, SUCH AS DUST. (SUPDAT) Neutralizing Agent:LOW NA+ACID NEUTRALIZERS. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE. OUTSIDE OR DETACHED STORAGE IS PREFERRED. INSIDE STORAGE SHOULD BE IN A STANDARD FLAMMABLE LIQUIDS STORAGE ROOM OR CABINET. SPERATE FROM OXIDIZING MATERIALS. STORAGE A ND USE AREAS SHOULD BE NO SMOKING AREAS. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS, LIQUID); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:(NIOSH APPROVED): FOR CONDITIONS OF USE WHERE EXPOSURE TO THE SUBSTANCE IS APPARENT, CONSULT AN INDUSTRIAL HYGIENIST. FOR EMERGENCIES, OR INSTANCES WHERE THE EXPOSURE LEVELS ARE NOT KNOWN, USE A FULL- FACEPIECE POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR. WARNING: AIR PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES. Ventilation:SYS OF LOC &/GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS AS LOW AS POSS. LOC EXHAUST VENT IS GENERALLY PREF BECAUSE IT CAN CNTROL EMISSIONS OF CONTAM (OTHER INFO) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS, LAB COAT, APRON OR COVERALS, AND APPROPRIATE, TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SPILL PROC: DO NOT FLUSH TO SEWER! US REGS (CERCLA) REQ REPORTING SPILLS & RELEASES TO SOIL, H*2O & AIR IN EXCESS OF REPORTABLE QTIES. TOLL FREE NUMBER FOR US COAST GUARD NATIONAL RESPONSE CENTER IS ( 800) 424-8802. J T BAKER NEUTRASOR(TM) OR TEAM(TM) 'LOW NA+' ACID NEUT ARE REC FOR SPILLS OF THIS PROD. ================== Physical/Chemical Properties ================== Boiling Pt:=162.C, 323.6F Melt/Freeze Pt:<-7.C, 19.4F Vapor Pres:(MM HG): 0.43 @ 20C (68F) Vapor Density:3.0(AIR=1) Evaporation Rate & Reference:NO INFORMATION FOUND. Solubility in Water:COMPLETELY SOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; UNPLEASANT RANCID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM OR OTHER LIGHT METALS, CHROMIUM TRIOXIDE, AND OXIDIZING MATERIALS. THE SOLUTION IN WATER IS ACID, REACTS WITH BASES, AND IS CORROSIVE. Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:INVESTIGATED AS A MUTAGEN. SKIN, RABBIT LD50:530 UL/KG; IRRITATION DATA, STANDARD DRAIZE TEST, EYE, RABBIT, OPEN: 250 UG - SEVERE. INGREDIENT: BUTYRIC ACID (107-92-6). ===================== Ecological Information ===================== Ecological:ENVIRON FATE: WHEN RLSD INTO SOIL, THIS MATL IS NOT EXPECTED TO LEACH INTO GROUNDWATER. WHEN RLSD INTO SOIL, THIS MATL IS NOT EXPECTED TO EVAP SIGNIFICANTLY. WHEN RLSD INTO H*2O, THIS MATL IS EXPECTED TO READILY BIODEGRATE. WHEN RLSD INTO H*2O, THIS MATL IS NOT EXPECTED TO EVAPORATE SIGNIFICANTLY. WHEN RLSD INTO H*2O, THIS MATL IS EXPECTED TO HAVE A HALF-LIFE OF GREATER THAN 30 DAYS. WHEN RLSD INT O AIR, THIS MATL IS EXPECTED TO BE READILY DEGRADED BY REACTION W/PHOTOCHEMICALLY PROD HYDROXYL RADICALS. WHEN RLSD INTO AIR, THIS MATL IS EXPECTED TO HAVE A HALF-LIFE BETWEEN 1 & 10 DAYS. (OTHER INFO ) ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP & APPRVD WASTE FACILITY. ALTHOUGH NOT LISTED RCRA HAZ WASTE, THIS MATL MAY EXHIBIT ONE/MORE CHARACT OF HAZ WASTE & REQUIRE APPROP ANALYSIS TO DETERM SPECIFIC DISP REQUIREMENTS. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. (OTHER INFO) =================== MSDS Transport Information =================== Transport Information:DOMESTIC (LAND, DOT): PROPER SHIPPING NAME: BUTYRIC ACID. HAZARD CLASS: 8, UN/NA: UN2820. PACKING GROUP: III. INFORMATION REPORTED FOR PRODUCT/SIZE: 500ML. INTERNATIONAL (WATER, I.M.O.): PROPER SHIPPI NG NAME: NORMAL-BUTYRIC ACID. HAZARD CLASS: 8, UN/NA: UN2820. PACKING GROUP: III. INFORMATION REPORTED FOR PRODUCT/SIZE: 500ML. INTERNATIONAL (AIR, I.C.A.O.): PROPER SHIPPING NAME: NORMAL-BUTYRIC ACI D: HAZARD CLASS: 8, UN/NA: UN2820. PACKING GROUP: III. INFORMATION REPORTED FOR PRODUCT/SIZE: 500ML. ===================== Regulatory Information ===================== SARA Title III Information:BUTYRIC ACID (107-92-6): FEDERAL, STATE & INTERNATIONAL REGULATIONS: PART 1: SARA 302 AND SARA 313. BUTYRIC ACID (107-92-6): FEDERAL, STATE & INTERNATIONAL REGULATIONS: PART 2: CERCLA: 5000. SARA 311/ 312. Federal Regulatory Information:CHEMICAL INVENTORY STATUS PART 1: BUTYRIC ACID (107-92-6): TSCA, EC, JAPAN, AUSTRALIA. CHEMICAL INVENTORY STATUS PART 2: BUTYRIC ACID (107-92-6): CANADA, KOREA, DSL, NDSL, PHIL. AUSTRALIAN HAZCHEM COD E: 2R. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL OF THE INFORMAI TON REQUIRED BY THE CPR. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.'