FISHER SCIENTIFIC -- SODIUM BROMIDE, S-255 -- 6810-00N039743
===================== Product Identification ===================== Product ID:SODIUM BROMIDE, S-255 MSDS Date:04/06/1994 FSC:6810 NIIN:00N039743 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ING 14: MORE SEV INVOLVEMENT IN WHICH ORAL MEDICATION IS IMPOSS, GIVE NORM SALINE, 1 LITER EVERY 8 HOURS (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: INTRAVENOUSLY TO MAX OF 2 LITERS DAILY. SODIUM CHLORIDE THERAPY MUST BE CONTINUED UNTIL BLOOD BROMIDE (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: LEVEL DROPS BELOW 50 MG/DL. SIMULTANEOUS ADMIN OF DIURETICS IS ALSO USEFUL (DREISBACH, HANDBOOK OF (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: POISONING, 12TH EDITION). ANTIDOTE SHOULD BE ADMINISTERED BY QUALIFIED MEDICAL PERSONNEL. RTECS #:9999999ZZ Ingred Name:RESP PROT: SPECIFIC OPERATION, MUST NOT EXCEED WORKING LIMS OF RESP & MUST BE APPRVD BY NIOSH. ANY DUST & MIST (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: RESP; ANY AIR-PURIFYING RESP W/HIGH-EFFICIENCY PARTICULATE FILTER; ANY POWERED AIR-PURIFYING RESP W/DUST(ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: & MIST FILTER; ANY POWERED AIR-PURIFYING RESP W/HIGH-EFFICIENCY PARTICULATE FILTER; ANY TYPE 'C' SUPP- (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: AIR RESP OPERATED IN PRESS-DEMAND/OTHER POS PRESS/CONTINUOUS-FLOW MODE; ANY SCBA. FOR FIREFIGHTING & (ING 23) RTECS #:9999999ZZ Ingred Name:ING OTHER IMMED DANGEROUS TO LIFE/HLTH CNDTNS: ANY SCBA W/FULL FACEPIECE & OPERATED IN PRESS-DEMAND/OTHER POS- (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23: PRESS MODE. ANY SUPP-AIR RESP W/FULL FACEPIECE & OPERATED IN PRESS-DEMAND/OTHER POS-PRESS MODE IN (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24: COMBINATION W/AUXILIARY SCBA OPERATED IN PRESS-DEMAND/OTHER POSITIVE-PRESSUDE MODE. RTECS #:9999999ZZ Ingred Name:SODIUM BROMIDE CAS:7647-15-6 RTECS #:VZ3150000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: DELUSIONS & HALLUCINATIONS MAY OCCUR. HYPERACTIVITY, SLUGGISH/ABSENT DEEP TENSION REFLEXES, GENERALIZED (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: WEAK, ABSENCE OF SEXUAL DESIRE & TRANSITORY SCHIZOPHRENIA HAVE ALSO BEEN REPORTED. OTHER EFTS MAY INCL (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: INCRD INTRACRANIAL PRESS, PAPILLEDEMA & HYPERTENSION. CONTINUED EXPOS MAY RSLT IN STUPOR & COMA. SKIN (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: MANIFESTATIONS MAY INCL ACNEIFORM, NODULAR/ERYTHEMATOUS RASH. EARLY LESIONS MAY INCL PAPULES, PUSTULES, (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: EDEMATOUS PLAQUES & ULCERS. CLASSIC CUTANEOUS SIGN OF BROMISM IS A PUSTULE-STUDDED, ECTHYMA-LIKE PLAQUE (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: ON LEGS. OTHER SYSTEMIC EFTS MAY INCL RHINITIS, BRONCH IRRIT, LACRIMATION, CONJ, BLEPHARITIS, INCR IN (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: PUPIL SIZE, SUBNORM RXNS TO LIGHT/ACCOMODATION, DISTURB OF COLOR VISION & VISUAL HALLUCINATIONS. (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: DISCONTINUATION OF EXPOS WILL NORM RSLT IN REVERSAL OF SYMPS. MATERNAL EXPOS MAY RSLT IN HYPOTONIA IN NEONATES. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: IMMED. INGEST: TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. IF VOMIT OCCURS, KEEP HEAD (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: LOWER THAN HIPS TO PVNT ASPIR. ANTIDOTE: THE FOLLOWING ANTIDOTE HAS BEEN REC. HOWEVER, THE DECISION AS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: TO WHETHER SEV OF POIS REQUIRES ADMIN OF ANY ANTIDOTE & ACTUAL DOSE REQUIRED SHOULD BE MADE BY QUALIFIED(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: MED PERS. BROMIDE POISONING: GIVE SODIUM CHLORIDE, 1 GRAM ORALLY EVERY HR IN WATER/SALT TABLETS; FOR (ING 15) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 3500 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:MOD TOX BY INGEST. TARGET EFTS: POIS MAY AFFECT SKIN & GI SYS & CNS. ACUTE: INHAL: DUSTS MAY CAUSE MUC MEMB IRRIT. INGEST: POIS BY ACUTE EXPOS IS RARE BECAUSE BROMIDES IRRITATE GI MUCOSA WHEN INGESTED IN LGE AMTS AS A SINGLE DOSE & CAUSE IMMED ABDOM PAIN, NAUS & VOMIT. HOWEVER, IN EVENT OF KIDNEY DMG, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: SYSTEMIC POIS MAY OCCUR BY SINGLE DOSE & POSS CAUSE PARAL & COMA. CHRONIC: INHAL: SYSTEMIC EFTS DUE TO INGEST & SUBSEQUENT EXCRETION OF BROMIDE ION THRU RESP TRACT MAY CAUSE RHINITIS & BRONC H IRRIT. INGEST: RPTD/PRLNG INGEST OF BROMIDES MAY CAUSE "BROMISM" WHICH MOST FREQUENTLY AFFECTS GI SYS, CNS & (SUP DAT) Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED LIVER FUNCTION. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, PERFORM ARTF RESP. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LGE AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN IMMED. EYES: WASH IMMED W/LGE AMTS OF WATER/NORM SALINE, OCCAS (ING ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . NO ACUTE HAZARD. MOVE CONTR FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS/DUSTS; KEEP UPWIND. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:THE FOLLOWING RESPS ARE REC BASED ON INFO FOUND IN PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. THEY ARE RANKED IN ORDER FROM MIN TO MAX RESP PROT. SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVELS FO UND IN WORK PLACE, MUST BE BASED ON (ING 19) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING THIS SUBSTANCE. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:PROVIDE LOCAL EXHAUST VENTILATION SYSTEM. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . APPROP PROT (IMPERVIOUS) CLTHG & EQUIP TO PVNT RPTD/PRLNG SKIN CONT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 6.5-8.0 (SOLN). EFTS OF OVEREXP: SKIN. GI DISTURB MAY INCL NAUS & VOMIT FROM GASTRIC IRRIT, FOUL BREATH, ANOREXIA, WT LOSS, DEHYDRATION & CONSTIP. NEUROLOGICAL MANIFESTATIONS MAY INCL HDCH, APATHY , SLURRED SPEECH, DECRD MEMORY, DROW, IMPAIRED INTELLECTUAL CAPACITY & EMOTIONAL CTL, TREMULOUSNESS & ATAXIA. (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:2534F,1390C Melt/Freeze Pt:M.P/F.P Text:1377F,747C Spec Gravity:3.203 pH:SUPDAT Solubility in Water:116% @ 50C Appearance and Odor:WHITE CUBIC, HYGROSCOPIC CRYSTALS OR POWDER WITH A SALINE, BITTER TASTE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ALKALOIDAL SALTS, HEAVY METAL SALTS: INCOMPATIBLE. BROMINE TRIFLUORIDE: RAPIDLY ATTACKED. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC AND HAZARDOUS FUMES OF HYDROGEN BROMIDE AND SODIUM OXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN DISPOSING OF THIS SUBSTANCE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.