SHERWIN-WILLIAMS -- 1614 HI-HEAT BLACK, KRYLON HIGH HEAT (SUPP DATA) -- 8010-01-142-1073
===================== Product Identification ===================== Product ID:1614 HI-HEAT BLACK, KRYLON HIGH HEAT (SUPP DATA) MSDS Date:09/01/1996 FSC:8010 NIIN:01-142-1073 === Responsible Party === Company Name:SHERWIN-WILLIAMS Address:31500 SOLON RD City:SOLON State:OH ZIP:44139 Country:US Info Phone Num:800-247-3270 Emergency Phone Num:216-566-2917 CAGE:DO642 === Contractor Identification === Company Name:KRYLON INDUSTRIAL Box:UNKNOW CAGE:KRYLX Company Name:SHERWIN-WILLIAMS CO THE SPECIALTY DIV. Address:6830 COCHRAN RD. Box:6709 City:SOLON State:OH ZIP:44139-3908 Phone:216-292-7400 CAGE:DO642 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE. VP:760. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 18% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:22. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 34% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BUTYL ALCOHOL; (1-BUTANOL) (SARA 313) (CERCLA). VP:5.5. CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 1% OSHA PEL:100 PPM ACGIH TLV:50 PPM, S, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE (SARA 313) (CERCLA). VP:180. CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 36% OSHA PEL:1000 PPM ACGIH TLV:750 PPM;1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 2% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:VOLATILE ORGANIC COMPOUNDS (BAAQMD RULE 49): 54.5% (WT); 3.45 LBS/GAL. RTECS #:9999999VO Ingred Name:SUPP DATA:APPARENT. OBTAIN MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS CAN BE HARMFUL/FATAL. WARNING:THESE PRODS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CNTN CHEM(S) KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS/OTHER REPRO HARM. NOTE:TOLUENE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO HAZARDS. SEEK CONSULTATION FROM APPROP HEALTH PROFESSIONALS (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:CONCERNING LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE INFORMATION . RTECS #:9999999ZZ Ingred Name:OTHER PREC:CONSULT NFPA CODE. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO TEMP >120F. HEAT FROM (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ADDN OF REDUCERS/OTHER ADDITIVES TO THIS PROD MAY (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:SUBSTANTIALLY ALTER COMPOSITION & HAZS OF PROD. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:CONT W/SKIN & EYES. THESE COATINGS MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC(ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS, VOL 65, PG 149, 1996:GROUP 2B. Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRO SYSTEMS. REPORTSHAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. (ING 8) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOHTING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F,<-18C Lower Limits:1% Upper Limits:36.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS REQS (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:NFPA CODE 30B - LEVEL 3 AEROSOLS. CONTENTS ARE EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. USE APPRVD BONDING & GROUNDING PROCS. Other Precautions:VAPS WILL ACCUM READILY & IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. (ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR NIOSH APPRVD PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING DRIED FILM, WEAR A NIOSH APPRVD DUST/MIST RESP FOR PROT (SUPDAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA) Protective Gloves:CHEMICAL RESISTANT GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:RESISTANT PAINTS. FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. RESP PROT:AGAINST NON-VOLAT INGS. VENT:1910.94, 1910.107, 1910.108. EX PLO HAZ:SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED (ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<395F,<202C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.76 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZ AS DEFINED UNDER RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE CNTNR. DISPOSE O F I/A/W FED, STATE & LOC REGS REGARDINGPOLLUTION. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.