MALLINCKRODT INC -- POTASSIUM DICHROMATE -- 6810-00-136-3000
===================== Product Identification ===================== Product ID:POTASSIUM DICHROMATE MSDS Date:04/06/1989 FSC:6810 NIIN:00-136-3000 === Responsible Party === Company Name:MALLINCKRODT INC Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:606-987-7000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM BICHROMATE (SARA III) CAS:7778-50-9 RTECS #:HX7680000 Other REC Limits:SEE ABOVE OSHA PEL:C,0.1 MG/M3 CRO3 ACGIH TLV:0.5 MG CR/M3; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL:MAY CAUSE IRRIT TO RESP TRACT,COUGHING,WHEEZING,FEVER,HDCH,&LABORED BRTH.MAY PRODUCE PULM SENSIT.INGEST:MAY CAUSE ABDOM PAIN,VOMIT,DIZZ,INTENSE THIRST,FEVER,COMA,&LIVER DMG.DEATH MAY OCCUR FROM CIRCULATORY COLLAPSE/RENAL FAILURE.EST LETHAL DOSE 5 GR.SKIN:CORROSIVE.MAY CAUSE IRRIT,ULCERATION,&SCARRING.(SEE BELOW) Explanation of Carcinogenicity:MUTATION REFERENCES CITED;REPRODUCTIVE DATA CITED.DETERMINATION-ANIMAL/INADEQUATE DATA(IARC23,30280). Effects of Overexposure:SKIN MAY BECOME SENSIT.ABSORPTION THRU SKIN MAY CAUSE SYSTEMIC POISONING;SYMP MAY PARALLEL INGEST.EYE:CORR.MAY CAUSE SEV IRRIT,REDNESS,PAIN,&CONJUNCT.CHRONIC EXP:RPTD/PRLNG SKIN CONT MAY CAUSE ECZEMAT OUS DERM.RPTD/PRLNG INHAL OF DUST MAY CAUSE ULCERATION,BLEEDING,&PERFORATION OF NASAL SEPTUM. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.IF NOT BRTH,GIVE ARTF RESP.IF BRTH IS DFCLT,GIVE 0*2.CALL MD.INGEST:INDUCE VOMIT IMMED BY GIVING TWO GLASSES OF WATER&STICKING FINGER DOWN THROAT.NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON.CALL MD.SKIN:IMMED FLUSH W/WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTH&SHOES.CALL MD.EYE:WASH EYES W/WATER FOR AT LEAST 15 MIN,LIFTING LOWER&UPPER EYELIDS OCCASNLY.GET MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:FLOOD W/LGE AMTS OF WATER.WATER SPRAY MAY BE USED TO KEEP FIRE EXPOS CONTR COOL.DO NOT ALLOW WATER TO RUN OFF TO SEWER. Fire Fighting Procedures:IN EVENT OF FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SCBA WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NOT COMBUST,STRONG OXIDIZ&HEAT OF RXN W/REDUCING AGENTS/COMBUST CAUSES IGNIT.RELS 0*2 UPON DECOMP WHICH ENHANCES COMBUST.CONT W/OXIDZ SUBSTANCES EXTREM VIOLENT. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA OF LEAK/SPILL.CLEAN-UP PERS REQ PROT CLTHG&RESP PROT FROM DUST.SPILLS:PICK UP&PLACE IN SUITABLE CONTR FOR RECLAMATION/DISP IN METH THAT DOES NOT GENERATE DUST.DISP:WHAT CANNOT BE SAVED FOR R ECLAMATION MAY BE DISP IN A RCRA APPRVDFACILITY. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DMG.STORE IN DRY LOCATION SEPERATE FROM COMBUST,ORG OR OTHER READILY OXIDIZABLE MATL.AVOID STORAGE ON WOOD FLOORS. Other Precautions:WEAR SPECIAL PROT EQUIP FOR MAINTENANCE BREAK-IN OR WHERE EXPOS MAY EXCEED ESTABLISHED EXPOS LEVELS.AVOID CROSS-CONTAMINATION OF STREET CLOTHES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED,A DUST/MIST RESP WITH CHEMICAL GOGGLES MAY BE WORN,IN GENERAL,UP TO TEN TIMES THE TLV.CONSULT RESPIRATOR SUPPLIER FOR LIMITATIONS.ALTERNATIVELY,A SUPPLIED AIR FULL FACEPIECE RES PIRATOR OR AIRLINED HOOD MAY BE WORN. Ventilation:LOCAL&/OR GENERAL EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. (SEE SUPP DATA) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING,INCLUDING BOOTS,GLOVES,LAB COAT,APRON OR COVERALLS TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH HANDS,FACE,FOREARMS&NECK WHEN EXITING RESTRICTED AREAS.SHOWER,DISP OF OUTER CLTH.EYE WASH FOUNTAIN&QUICK DRENCH FAC Supplemental Safety and Health VENTILATION:LOCAL EXHAUST VENTILATION IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL THE EMISSIONS OF THE CONTAMINANT AT ITS SOURCE,PREVENTING DISPERSION OF IT INTO THE GENERAL WORK AREA.PLEASE REFER T O THE ACGIH DOCUMENT,"INDUSTRIAL VENTILATION,A MANUAL OF RECOMMENDED PRACTICES",MOST RECENT EDITION,FOR DETAILS. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:500C(932F) Melt/Freeze Pt:M.P/F.P Text:398C(784F) Spec Gravity:2.69 Solubility in Water:6.5% @ 10C (50F) Appearance and Odor:ODORLESS, ORANGE-RED CRYSTALS OR POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS, ACETONE PLUS SULFURIC ACID, HYDRAZINE, AND HYDROXYLAMINE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:EMITS OXYGEN AND TOXIC FUMES OF CHROMIUM TRIOXIDE WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT FLUSH TO THE SEWER. ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. REMOVE AND DISPOSE OF ANY SPILLED DICHROMATES; DO NOT RETURN TO ORIGINAL CONTAINERS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.