MALLINCKRODT -- CUPROUS CHLORIDE -- 6810-00N045500
===================== Product Identification ===================== Product ID:CUPROUS CHLORIDE MSDS Date:12/08/1992 FSC:6810 NIIN:00N045500 === Responsible Party === Company Name:MALLINCKRODT Box:800 City:PARIS State:KY ZIP:40362 Country:US Info Phone Num:315-539-1600 Emergency Phone Num:314-539-1600 CAGE:ZA916 === Contractor Identification === Company Name:MALLINCKRODT MEDICAL, INC Address:2703 WAGNER PLACE Box:M City:MARYLAND HEIGHTS State:MO ZIP:63043 Country:US Phone:314-770-7800 CAGE:ZA916 Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:COPPER (I) CHLORIDE; (CUPROUS CHLORIDE). PEL: 0.1 MG/M3 FUME;1 DUST (CU). TLV: 0.2 MG/M3 FUME;1 DUST (CU) CAS:7758-89-6 RTECS #:GL6990000 OSHA PEL:SEE INGREDIENT NAME ACGIH TLV:SEE INGREDIENT NAME Ingred Name:SUPP DATA: & IRRIT OF THE MUCOUS MEMBRANES. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: 15 MIN. GET MED ATTN IF IRRITATION DEVELOPS OR PERSISTS. RTECS #:9999999ZZ Ingred Name:VENT:LOC THE EXHST VENT IS GENERALLY PREFERRED BECAUSE IT CAN CONTROL THE EMISSIONS OF THE CONTAM AT ITS SOURCE, (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: PREVENTING DISPERSION OF IT INTO THE GENERAL WORK AREA. PLEASE REFER TO THE ACGIH DOCUMENT, "INDUST VENT, (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: A MANUAL OF RECOMMENDED PRACTICES", MOST RECENT EDITION, FOR DETAILS. RTECS #:9999999ZZ Ingred Name:EYE PROT: LENGTH FACESHIELD . RTECS #:9999999ZZ Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 140 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL:CAUSES IRRIT TO UPPER RESP TRACT, SYMPS MAY INCL COUGHING, SORE THROAT, & SHORTNESS OF BREATH. MAY ALSO CAUSE SYMPS SIMILAR TO THE COMMON COLD; INCL CHILLS & STUFFINESS OF THE HEAD. INGEST:MAY C AUSE BURNING PAIN IN MOUTH, ESOPHAGUS, & STOMACH. HEMORRHAGIC GASTRITIS, NAUSEA, VOMIT, ABDOMINAL PAIN,(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:METALLIC TASTE, & DIARR MAY OCCUR. IF VOMIT DOES NOT OCCUR IMMED, SYSTEMIC COPPER POIS MAY OCCUR. SYMPS MAY INCL CAPILLARY DAMAGE, HDCH,COLD SWEAT, WEAK PULSE, KIDNEY & LIVER DMG, CNS EXCITAT ION FOLLOWED BY DEPRESSION, JAUNDICE, CONVUSLSIONS, PARALYSIS & COMA. DEATH MAY OCCUR FROM SHOCK OR RENAL (SUPP DATA) Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR IMPAIRED LIVER, KIDNEYS, OR PULMONARY FUNCTION OR PRE-EXISTING WILSON'S DISEASE MAY BE MORE SUSCEPTIBLE TO THE EFTS OF THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:INGEST:INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER/MILK IF AVAIL & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE O2. EYE:IMMED FLUSH W/ PLENTY OF H2O FOR @ LST 15 MIN. IN ALL CASES CALL MD. SKIN:REMOVE ANY CONTAM CLTHG. WIPE OFF EXCESS FROM SKIN. WASH W/SOAP & H2O FOR @ LST(ING 3 ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROT EQUIP . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. REACTIONS WITH INCOMPATIBILITIES MAY POSE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA OF LEAK/SPILL. CLEAN-UP PERSONNEL REQUIRED PROT CLTHG & RESP PROT FROM DUST. SPILLS: PICK UP & PLACE IN SUITABLE CNTNR FOR RECLAIM/DISP IN A METHOD THAT DOES NOT GENERATE DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. Other Precautions:KEEP IN A TIGHTLY CLOSED CNTNR, STORE IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES. CNTCT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS MAT ERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED A NIOSH/MSHA APPRVD DUST/MIST RESP W/CHEM GOGG MAY BE WORN, IN GENERAL, UP TO 10 TIMES THE TLV. CONSULT RESP SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, NIOSH/MSHA APPRVD FULL FACEPIEC E RESP/AIRLINED HOOD MAY BE WORN. Ventilation:A SYS OF LOC &/OR GEN EXHST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS. (ING 4) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPVD CHEM SFTY GOGGS W/FULL (ING 7 Other Protective Equipment:CLEAN BODY-COVERING CLOTHING. MAINT ANSI APPVD EYE WASH FOUNT & QCK-DRENCH FACIL IN WRK AREA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EFTS OF OVEREXP:FAILURE. EYE:CAUSES IRRIT, REDNESS, PAIN, DISCOLORATION & DMG. CHRONIC: PRLNGD/RPTD SKIN EXPOSURE MAY CAUSE DERM. PRLNGD/RPTD EXPOSURE TO DUSTS OF COPPER SALTS MAY CAUSE DISCOLORATION OF SKIN/HAIR, ULCERATION & PERFORATION OF THE NASAL SEPTUM, RUNNY NOSE, METALLIC TASTE, & ATROPHIC CHANGES (ING 2) ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:2491F,1366C Melt/Freeze Pt:M.P/F.P Text:806F,430C Vapor Pres:0.975@546C Spec Gravity:4.14 Solubility in Water:0.62G/100ML WATER Appearance and Odor:WHITE CRYSTALS. ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES POTASSIUM, ACETYLENE, HYDRAZINE, AND NITROMETHANE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:EMITS TOXIC FUMES OF CHLORINE WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DISPOSED IN A RCRA APPROVED WASTE DISPOSAL FACILITY. DO NOT FLUSH TO SEWER. TOXIC TO FISH. ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.